Negative bias-induced threshold voltage instability and zener/interface trapping mechanism in GaN-based MIS-HEMTs

We investigate the instability of threshold voltage in D-mode MIS-HEMT with in-situ SiN as gate dielectric under different negative gate stresses.The complex non-monotonic evolution of threshold voltage under the negative stress and during the recovery process is induced by the combination effect of two mechanisms.The effect of trapping behavior of interface state at SiN/AlGaN interface and the effect of zener traps in AlGaN barrier layer on the threshold voltage instability are opposite to each other.The threshold voltage shifts negatively under the negative stress due to the detrapping of the electrons at SiN/AlGaN interface,and shifts positively due to zener trapping in AlGaN barrier layer.As the stress is removed,the threshold voltage shifts positively for the retrapping of interface states and negatively for the thermal detrapping in AlGaN.However,it is the trapping behavior in the AlGaN rather than the interface state that results in the change of transconductance in the D-mode MIS-HEMT.     

The First Heteropentanuclear Extended Metal‐Atom Chain: [Ni+Ru25+Ni2+Ni2+(tripyridyldiamido)4(NCS)2]

This study develops the first heteropentametal extended metal atom chain (EMAC) in which a string of nickel cores is incorporated with a diruthenium unit to tune the molecular properties. Spectroscopic, crystallographic, and magnetic characterizations show the formation of a fully delocalized Ru₂⁵⁺ unit. This [Ru₂]‐containing EMAC exhibits single‐molecule conductance four‐fold superior to that of the pentanickel complex and results in features of negative differential resistance (NDR), which are unobserved in analogues of pentanickel and pentaruthenium EMACs. A plausible mechanism for the NDR behavior is proposed for this diruthenium‐modulated EMAC.     

Rotaxanes Synthesized Through Sodium‐Ion‐Templated Clipping of Macrocycles Around Nonconjugated Amide and Urea Functionalities

A single urea or amide functionality in a dumbbell‐shaped guest can be “clipped” by a macrocycle generated from a diamine and a dialdehyde through the templating effect of a Na⁺ ion (see scheme). The resulting imine‐containing rotaxanes can then be reduced to allow isolation of stable amine‐based rotaxanes.     

Synthesis and applications of sulfur-substituted cis-hexahydro-2-quinolinones

An efficient synthesis of sulfur-substituted cis-hexahydro-2-quinolinones has been achieved by an aza-Diels^_Alder reaction of p-toluenesulfonyl isocyanate with a diene precursor derived from a bicyclic 3-sulfolene via ring-closing metathesis. Some synthetic tranformations have also been carried out.     

颜色可调的高荧光CdTe量子点的水相合成

以亚碲酸钠为碲源,硼氢化钠为还原剂,一步合成了巯基丁二酸(MSA)稳定的CdTe量子点.研究了反应液pH值、镉与碲的摩尔比及镉与巯基丁二酸的摩尔比等实验条件对CdTe量子点体系荧光量子产率的影响,并用荧光光谱、X射线粉末衍射及透射电子显微镜等对其进行了表征.结果表明,CdTe量子点具有闪锌矿结构,形貌呈球状;在pH=1...     

Synthesis and Structure Characterization of 2‐(Dimethylaminomethyl)pyrrolate and 2,5‐Bis(dimethylaminomethyl)pyrrolate Zirconium Complexes

Tetrakis(diethylamido)zirconium reacts with 2‐(dimethylamino)methyl pyrrole (DMAMP) and 2,5‐[bis(dimethylamino)methyl]pyrrole (BDMAMP) to give Zr(NEt)₂(DMAMP)₂ 1 and Zr(NEt)₃(BDMAMP) 2 , respectively. Both 1 and 2 have been characterized by ¹H and ¹³C NMR spectroscopies and 1 has also been characterized by X‐ray crystallography. Complex 1 shows an agostic interaction between Zr and H(21A) in solid state that is not sustained in solution. Reacting 1 with 2 equivalents of trimethylsilyl chloride in toluene yields ZrCl₂(DMAMP)₂ 3 in 75% yield which was characterized by ¹H and ¹³C NMR spectroscopies.     

矢量声纳高速运动目标稳健高分辨方位估计

针对水声矢量信号处理框架中的高速运动目标低信噪 比小快拍条件下的稳健高分辨方位估计问题, 将压缩感知技术应用于水声矢量信号空间谱估计模型中. 结合声矢量传感器结构特性, 探讨了基于声压振速联合处理的广义时域滤波方法; 结合矩阵空域预滤波理论, 设计了基于阻带约束通带均方误差最大值最小的空域滤波器, 研究了矢量声纳空域预滤波方法; 结合以上分析, 提出了基于压缩感知技术的时空联合滤波高分辨方位估计方法, 给出了方法的数学模型、物理解释及具体实施步骤.理论分析和计算机仿真试验表明, 新方法对于小快拍数 条件下的矢量声纳高速运动目标高分辨方位估计问题, 具有较低的双目标分辨门限和较高的估计精度, 有着良好的应用前景.湖上试验验证了方法的有效性. 关键词： 声矢量传感器 空间谱估计 时空滤波 压缩感知